No-slip, slip and friction at fluid-solid interfaces: Concept of adsorption layer (2502.18380v1)

Abstract: When a fluid contacts solid surfaces, it can spread or slide, and the motion of the contact line involves a complex interplay between hydrodynamic and thermodynamic effects. Hydrodynamic theories, like the Huh & Scriven and Cox & Voinov models, assumeno-slip boundary condition, neglecting the macroscopic fluid slip at the fluid-solid interface. However, they cannot explain the contact line motion during droplet spreading whichthermodynamic theories is attribute to the microscopic surface diffusion of fluid molecules. To bridge these perspectives, we heed the physical origin of slip phenomenon by employing energy minimization principles to establish a force balance between solid-fluid friction, thermodynamic force, and viscous stress at the fluid-solid contact region. Our analysis reveals that slip is an intrinsic property, just like molecular surface diffusion, is also governedfluid-solid intermolecular interactions. Based on our model with slip, we extend the classical Huh & Scriven and Cox & Voinov theories by incorporating friction, enabling a more comprehensive understanding of droplet slide and kinetic induced contact angle hysteresis (CAH). Our results demonstrate that solid-fluid friction plays a vital role in momentum transfer between the substrate and the droplet, therefore, modifies the droplet internal fluid flow during wetting drastically. Under strong friction, classical wetting predictions with CAH are recovered, whereas weak friction suppresses internal fluid motion, leadingthe disappearance of CAH. These findings provide new insights into wetting dynamics, highlighting the importance of friction in slip behavior. This work has broad implications for droplet transport, surface engineering, and applications in microfluidics and coatings.