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Quantum-Centric Algorithm for Sample-Based Krylov Diagonalization (2501.09702v2)

Published 16 Jan 2025 in quant-ph, cond-mat.other, and physics.comp-ph

Abstract: Approximating the ground state of many-body systems is a key computational bottleneck underlying important applications in physics and chemistry. It has long been viewed as a promising application for quantum computers. The most widely known quantum algorithm for ground state approximation, quantum phase estimation, is out of reach of current quantum processors due to its high circuit-depths. Quantum diagonalization algorithms based on subspaces represent alternatives to phase estimation, which are feasible for pre-fault-tolerant and early-fault-tolerant quantum computers. Here, we introduce a quantum diagonalization algorithm which combines two key ideas on quantum subspaces: a classical diagonalization based on quantum samples, and subspaces constructed with quantum Krylov states. We prove that our algorithm converges in polynomial time under the working assumptions of Krylov quantum diagonalization and sparseness of the ground state. We then show numerical investigations of lattice Hamiltonians, which indicate that our method can outperform existing Krylov quantum diagonalization in the presence of shot noise, making our approach well-suited for near-term quantum devices. Finally, we carry out the largest ground-state quantum simulation of the single-impurity Anderson model on a system with $41$ bath sites, using $85$ qubits and up to $6 \cdot 103$ two-qubit gates on a Heron quantum processor, showing excellent agreement with density matrix renormalization group calculations.

Summary

  • The paper introduces SKQD, a method that merges Krylov and sample-based approaches to approximate ground state energies with provable polynomial convergence.
  • It leverages classical state sampling to reduce quantum circuit depth and enhance noise resilience, enabling effective simulations on early-fault-tolerant devices.
  • Experimental results on an 85-qubit processor demonstrate its scalability and record performance in simulating complex many-body quantum systems.

An Expert Overview of "Sample-based Krylov Quantum Diagonalization"

The paper "Sample-based Krylov Quantum Diagonalization" introduces an innovative quantum algorithm designed to approximate the ground state energies of many-body systems, which is a critical computational challenge in the realms of physics and chemistry. The authors offer this new method as a practical alternative to traditional quantum phase estimation for utilization on pre-fault-tolerant and early-fault-tolerant quantum devices.

Core Concepts

The presented work bridges two existing approaches: Krylov Quantum Diagonalization (KQD) and Sample-based Quantum Diagonalization (SQD). The classical KQD method constructs a Krylov subspace from time-evolved states starting from an initial reference state and thus reduces the dimensionality of the problem. The conventional approach often faces restrictions due to depth requirements in circuit implementations, which inhibit its application on contemporary quantum devices.

On the other hand, SQD leverages classical diagonalization techniques by sampling quantum states and has demonstrated proficiency in handling systems where the ground state is considerably sparse. It relies less on the quantum circuit executions — enabling suitability for short-depth circuits and accommodating larger systems than feasible with classical methods.

Methodology and Theoretical Insights

The authors propose a unification of the Krylov and sample-based methodologies, referred to as sample-based Krylov quantum diagonalization (SKQD). The theoretical backbone of this approach is the rigorous establishment of convergence conditions; it is shown to converge in polynomial time under specific conditions. Particularly, SKQD requires an initial state with a polynomial overlap with the true ground state along with a sparse ground state—defined in terms of alpha and beta sparsity conditions.

Quantitatively, in their theory, the authors derive an error bound for the ground state energy based on the overlap of the initial state with the ground state and other spectral properties of the Hamiltonian, demonstrating that favorable convergence rates can be achieved with their SKQD approach when sampling from Krylov states.

Numerical Experiments and Results

The practical utility of the SKQD method is validated through numerical simulations on lattice Hamiltonians, where it exhibits superior performance against existing KQD methods, especially in the presence of shot noise. Moreover, the paper reports experimental results achieved using an 85-qubit quantum processor to simulate a single-impurity Anderson model with remarkable alignment with density matrix renormalization group (DMRG) calculations.

One of the pivotal experimental accomplishments noted is conducting the largest ground-state quantum simulation to date on a quantum processor for a system with 41 bath sites, utilizing 85 qubits. These results underline the efficacy of the sample-based Krylov approach in handling complex quantum systems, far exceeding classical computational capabilities.

Implications and Future Directions

SKQD opens new research paths in quantum computing by combining reduced quantum resources' requirements with rigorous convergence guarantees under particular sparsity conditions. The presented approach leverages both classical and quantum computations deftly, pointing towards the potential for new hybrid quantum-classical algorithms for understanding quantum systems in condensed matter physics, quantum chemistry, and beyond.

Future developments may focus on refining the implementation of Krylov subspace sampling techniques, improving noise resilience, and further reducing circuit depth through more advanced error mitigation strategies. Furthermore, exploring SKQD’s adaptability to broader classes of problems, enhancing its scalability, and directly comparing its real-world performance with alternative variational and hybrid methods will constitute important research endeavors.

This paper contributes a substantial advancement to the theoretical and practical methodologies available for quantum computational tasks, reaffirming the potential of near-term quantum devices to address specific classes of problems previously thought to be within the exclusive domain of much larger quantum computers.