Structural Lubricity and Molecular Contamination: Rejuvenation, Aging, and Friction Switches

Abstract: Using atomic force microscopy experiments and molecular dynamics simulations of gold nanoislands on graphite, we investigate why ultra-small friction commonly associated with structural lubricity can be observed even under ambient conditions. Measurements conducted within a few days after sample synthesis reveal previously undiscovered phenomena in structurally lubric systems: rejuvenation, a drop in kinetic friction of an order of magnitude shortly after the onset of sliding; aging, a significant increase in kinetic friction forces after a rest period of 30 minutes or more; switches, spontaneous jumps between distinct friction branches. These three effects are drastically suppressed a few weeks later. Imaging of a contamination layer and simulations provide a consistent picture of how single- and double-layer contamination underneath the gold nanoislands as well as contamination surrounding the nanoislands affect structural lubricity but not lead to its breakdown.