Beyond Cavity Born-Oppenheimer: On Non-Adiabatic Coupling and Effective Ground State Hamiltonians in Vibro-Polaritonic Chemistry (2305.11153v4)

Abstract: The emerging field of vibro-polaritonic chemistry studies the impact of light-matter hybrid states known as vibrational polaritons on chemical reactivity and molecular properties. Here, we discuss vibro-polaritonic chemistry from a quantum chemical perspective beyond the cavity Born-Oppenheimer (CBO) approximation and examine the role of electron-photon correlation in effective ground state Hamiltonians. We first quantitatively review ab initio vibro-polaritonic chemistry based on the molecular Pauli-Fierz Hamiltonian in dipole approximation and a vibrational strong coupling (VSC) Born-Huang expansion. We then derive non-adiabatic coupling elements arising from both slow'' nuclei and cavity modes compared tofast'' electrons via the generalized HeLLMann-Feynman theorem, discuss their properties and re-evaluate the CBO approximation. In the second part, we introduce a crude VSC Born-Huang expansion based on adiabatic electronic states, which provides a foundation for widely employed effective Pauli-Fierz Hamiltonians in ground state vibro-polaritonic chemistry. The latter do not strictly respect the CBO approximation but an alternative scheme, which we name crude CBO approximation. We argue that the crude CBO ground state misses electron-photon entanglement relative to the CBO ground state due to neglected cavity-induced non-adiabatic transition dipole couplings to excited states. A perturbative connection between both ground state approximations is proposed, which identifies the crude CBO ground state as first-order approximation to its CBO counterpart. We provide an illustrative numerical analysis of the cavity Shin-Metiu model with a focus on non-adiabatic coupling under VSC and electron-photon correlation effects on classical activation barriers. We finally discuss potential shortcomings of the electron-polariton Hamiltonian when employed in the VSC regime.