Rapid in-situ quantification of rheo-optic evolution for cellulose spinning in ionic solvents (2303.08573v1)

Abstract: It is critical to monitor the structural evolution during deformation of complex fluids for the optimization of many manufacturing processes, including textile spinning. However, in situ measurements in a textile spinning process suffer from paucity of non-destructive instruments and interpretations of the measured data. In this work, kinetic and rheo-optic properties of a cellulose/ionic liquid solution were measured simultaneously while fibers were regenerated in aqueous media from a miniature wet spinline equipped with a customized polarized microscope. This system enables to control key spinning parameters, while capturing and processing the geometrical and structural information of the spun fiber in a real-time manner. We identified complex flow kinematics of a deformed fiber during the coagulation process via feature tracking methods, and visualized its morphology and birefringent responses before and during regeneration at varying draw ratios and residence time. Meanwhile, a three-dimensional physical rheological model was applied to describe the non-linear viscoelastic behavior in a complex wet-spinning process incorporating both shear and extensional flows. We subsequently compared the birefringent responses of fibers under coagulation with the transient orientation inferred from the rheological model, and identified a superposed structure-optic relationship under varying spinning conditions. Such structural characterizations inferred from the flow dynamics of spinning dopes are readily connected with key mechanical properties of fully-regenerated fibers, thus enabling to predict the spinning performance in a non-destructive protocol.