Cavity control of Excitons in two dimensional Materials (1810.02672v3)

Abstract: We propose a robust and efficient way of controlling the optical spectra of two-dimensional materials and van der Waals heterostructures by quantum cavity embedding. The cavity light-matter coupling leads to the formation of exciton-polaritons, a superposition of photons and excitons. Our first principles study demonstrates a reordering and mixing of bright and dark excitons spectral features and in the case of a type II van-der-Waals heterostructure an inversion of intra and interlayer excitonic resonances. We further show that the cavity light-matter coupling strongly depends on the dielectric environment and can be controlled by encapsulating the active 2D crystal in another dielectric material. Our theoretical calculations are based on a newly developed non-perturbative many-body framework to solve the coupled electron-photon Schr\"odinger equation in a quantum-electrodynamical extension of the Bethe-Salpeter approach. This approach enables the ab-initio simulations of exciton-polariton states and their dispersion from weak to strong cavity light-matter coupling regimes. Our method is then extended to treat van der Waals heterostructures and encapsulated 2D materials using a simplified Mott-Wannier description of the excitons that can be applied to very large systems beyond reach for fully ab-initio approaches.