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Astrochemistry of dust, ice and gas: introduction and overview (1411.5280v1)

Published 19 Nov 2014 in astro-ph.GA and astro-ph.EP

Abstract: A brief introduction and overview of the astrochemistry of dust, ice and gas and their interplay is presented, aimed at non-specialists. The importance of basic chemical physics studies of critical reactions is illustrated through a number of recent examples. Such studies have also triggered new insight into chemistry, illustrating how astronomy and chemistry can enhance each other. Much of the chemistry in star- and planet-forming regions is now thought to be driven by gas-grain chemistry rather than pure gas-phase chemistry, and a critical discussion of the state of such models is given. Recent developments in studies of diffuse clouds and PDRs, cold dense clouds, hot cores, protoplanetary disks and exoplanetary atmospheres are summarized, both for simple and more complex molecules, with links to papers presented in this volume. In spite of many lingering uncertainties, the future of astrochemistry is bright: new observational facilities promise major advances in our understanding of the journey of gas, ice and dust from clouds to planets.

Citations (61)

Summary

Overview of Astrochemistry: Dust, Ice, and Gas

The paper "Astrochemistry of dust, ice, and gas: introduction and overview," provides an extensive exploration of the intricate processes and interactions in astrochemistry, with a particular focus on the interplay between dust, ice, and gas within various astronomical environments. Authored by Ewine F. van Dishoeck, the paper explores the complex chemistry occurring in the interstellar medium (ISM), addressing both fundamental and advanced concepts relevant for researchers actively engaged in this field.

Interstellar Medium and Environmental Conditions

The ISM is characterized by a vast range of temperatures and densities, creating a unique backdrop for studying chemical reactions under extreme conditions. Dense molecular clouds, the birthplace of stars and planetary systems, host a rich chemistry despite traditionally low reaction probabilities predicted by standard chemical theories. The detection of diverse molecular species over the last few decades, including complex molecules even in high-redshift galaxies, underscores the dynamic and rich chemical activity within these clouds.

Formation and Evolution of Molecules

The paper emphasizes the shift from traditional gas-phase chemistry models to gas-grain chemistry, where the surface of dust grains plays a critical role in molecular synthesis. Surface processes enable reactions that are otherwise inefficient in the gas phase, facilitating the formation of complex organic molecules and prebiotic species. Recent findings suggest that many interstellar molecules are formed either on dust grain surfaces or through intricate gas-grain interactions, challenging erstwhile models that focused predominantly on gas-phase reactions.

Observational Advances and Implications

Recent observational advances, driven by cutting-edge telescopes like ALMA and Herschel, have provided unprecedented insights into the chemical processes in star-forming regions and protoplanetary disks. These observations have revealed the layered chemical structure within PDRs and identified new molecular species, including notably elusive compounds like ArH+^+ in various astrophysical environments. Observational data now allow researchers to probe complex molecules and mineral compositions within interstellar and circumstellar dust, providing critical information for understanding the material evolution from clouds to planetary systems.

Laboratory Studies and Theoretical Models

Laboratory astrochemistry complements astronomical observations by investigating surface reactions and gas-grain interactions at the molecular level. These experiments are fundamental for quantifying reaction rates and product distributions, offering a deeper understanding of the conditions that lead to complex molecule formation. Theoretical models, supported by computational chemistry, help simulate astrochemical processes, revealing reaction pathways and pointing towards areas where experimental confirmations are needed.

Prospects and Challenges in Astrochemistry

The interdisciplinary nature of astrochemistry paves the way for mutual enhancements between astronomy and chemistry, enriching both fields. Future developments hinge on further collaboration between laboratory studies and theoretical modeling to address lingering uncertainties, such as the mechanism behind extreme molecular deuteration and discrepancies in chemical modeling versus observational data.

The paper concludes with an optimistic outlook towards future research opportunities in astrochemistry, highlighting the potential of new observational facilities like ALMA and JWST to revolutionize our understanding of molecular complexity in space and the formation of potentially life-bearing planetary systems. This work acts as a cornerstone for ongoing discussions in the field, providing a comprehensive overview that both consolidates current knowledge and lays the groundwork for future exploration.

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