---
title: Kondo Breakdown Quantum Phase Transition
url: https://www.emergentmind.com/topics/kondo-breakdown-quantum-phase-transition
type: topic
---

# Kondo Breakdown Quantum Phase Transition

A Kondo breakdown quantum phase transition (QPT) is a zero-temperature critical point at which the Kondo entanglement between localized magnetic moments and conduction electrons is destroyed, resulting in a sudden reconstruction of the Fermi surface, emergent criticality beyond Gaussian order-parameter fluctuations, and often the emergence of new electronic or magnetic phases. This scenario, germane to heavy-fermion systems, moiré Kondo lattices, and engineered mesoscopic devices, fundamentally challenges the Landau paradigm: the order parameter dynamics alone do not suffice to characterize the transition, due to the collapse of a nonlocal and topological Kondo singlet amplitude at the QCP.

## 1. Microscopic Models and Order Parameters

The canonical Hamiltonian for the Kondo-breakdown QPT in heavy-fermion systems is the Kondo lattice model, given by
\[
H = \sum_{k,\sigma} \epsilon_k\,c_{k\sigma}^\dagger c_{k\sigma} + J_K\sum_{i} \mathbf{S}_i \cdot \mathbf{s}_{c,i} + \sum_{\langle ij \rangle} I_{ij}\,\mathbf{S}_i \cdot \mathbf{S}_j,
\]
where $c_{k\sigma}$ annihilates a conduction electron, $\mathbf{S}_i$ is a local moment (e.g., $f$-electron spin), $J_K$ is the Kondo exchange, and $I_{ij}$ (RKKY) is the intersite spin exchange [1303.4141, 1312.0764, 1012.5440].

The essential order parameters and scales for diagnosing Kondo breakdown include:
- **Kondo singlet amplitude** $b^* = \langle c^\dagger f \rangle$ or slave-boson condensate, whose vanishing signals breakdown.
- **Fermi surface volume**: jumps from large ($n_c+1$) to small ($n_c$ electrons per cell), with $n_c$ the conduction filling, at the critical point.
- **Dynamical spin susceptibility**: exhibits non-Gaussian scaling and $\omega/T$ collapse near the QCP.
- **An additional vanishing energy scale** $E_\text{loc}^*$ besides the magnetic gap, collapsing at the QCP.

In moiré Kondo lattices (e.g., AB-stacked MoTe$_2$/WSe$_2$) [2310.06044], the model is a density-tunable Anderson–Kondo lattice with local interactions, gate-tunable carrier density $x$, and competing scales $T_K$ (Kondo) and $J_\text{RKKY}$ (indirect exchange).

## 2. Theoretical Frameworks and Critical Scaling

Kondo-breakdown QCPs arise when the RKKY interaction dominates over Kondo screening, destroying the Kondo effect at the phase transition [1012.5440, 1303.4141, 1312.0764]. The critical theory is fundamentally distinct from the Hertz–Millis–Moriya (spin-density-wave, SDW) QCP:

- **EDMFT/Bose-Fermi Kondo Models**: The local moment is embedded in fermionic and bosonic self-consistently determined baths. The critical point is defined by simultaneous divergence of both the local ($\chi_\text{loc}$) and ordering-wavevector ($\chi(\mathbf{Q},0)$) spin susceptibilities [1303.4141, 1603.03829].
- **RG Flows**: In the Bose-Fermi Kondo model, the beta functions for $J_K$ and RKKY coupling $g$ admit a critical fixed point with nontrivial local spin susceptibility scaling, e.g., $\chi_\text{loc}(\tau)\sim\tau^{-\epsilon}$, with $\epsilon$ characterizing the bosonic bath spectrum [1312.0764].
- **Fractional Exponents**: Lattice susceptibility scales as
  \[
  \chi(\mathbf{q},\omega) = \frac{1}{f(\mathbf{q}) + A(-i\omega)^\alpha \mathcal{M}(\omega/T)},
  \]
  with $\alpha\approx0.75$ (extracted e.g. in CeCu$_{5.9}$Au$_{0.1}$), signaling non-Gaussian (local) criticality and contrasting with SDW exponents ($z=2$, mean field) [1303.4141, 1603.03829].
- **Fermi Surface Collapse**: The vanishing Kondo scale yields a discontinuous jump in FS volume, robustly observable in Hall and quantum oscillation experiments.

## 3. Global Phase Diagrams and Universality Classes

The global $T=0$ phase diagram in Kondo systems can be parametrized by (i) the ratio of Kondo screening to magnetic interaction (e.g., $\delta = T_K^0 / I$), and (ii) a parameter $G$ measuring quantum fluctuations (frustration, dimensionality) [1303.4141, 1312.0764]. Four phases generally appear:

| Phase    | Magnetic Order       | Kondo Screening | Fermi Surface Size  |
|----------|---------------------|-----------------|---------------------|
| $AF_S$   | Antiferromagnetic   | Destroyed       | Small               |
| $AF_L$   | Antiferromagnetic   | Intact          | Large               |
| $P_S$    | Paramagnetic        | Destroyed       | Small               |
| $P_L$    | Paramagnetic        | Intact          | Large               |

Transitions between these phases can occur via:
- **Direct Kondo-breakdown QCP** (Type I): $AF_S \leftrightarrow P_L$ with simultaneous Fermi surface jump and magnetic transition.
- **Indirect via $AF_L$ or $P_S$** (Types II / III): via SDW order of the heavy FL or via a spin-liquid/valence-bond insulator.

These universality classes are distinguished from conventional SDW QCPs by the presence of an additional vanishing energy scale $E_\text{loc}^*$, a fractional critical exponent $\alpha<1$, and local criticality (effectively $z\to\infty$ for the magnetic dynamics).

## 4. Experimental Signatures

Robust experimental manifestations of Kondo-breakdown QPTs include:
- **Fermi surface jump**: Quantized discontinuity in FS volume at the QCP, seen in de Haas–van Alphen, Hall coefficient, and ARPES [1303.4141, 1012.5440].
- **Diverging mass and vanishing coherence scale**: Enhanced effective mass and collapse of $T_K$ or $E_\text{loc}^*$ (e.g., divergence of $\sqrt{A}$, divergence of $\xi$) [2310.06044].
- **Non-Fermi-liquid thermodynamics**: $C/T\sim-\ln T$, linear-in-$T$ resistivity, Grüneisen ratio divergence [1303.4141, 1901.10411].
- **$\omega/T$ scaling and fractional exponents**: Neutron scattering finds critical spin responses scaling as $\chi''(\mathbf{Q},\omega)\sim\omega^{-\alpha}$ with $\alpha\approx0.75$ and $\omega/T$ collapse.
- **Thermopower collapse**: Seebeck coefficient $S/T$ exhibits a sharp drop at characteristic scale $E^*$ uniquely in the Kondo-breakdown scenario, while it varies smoothly in SDW criticality [1005.3354].
- **Transport and optical signatures**: Metal-insulator transitions with power-law resistivity ($R_{xx}\sim T^{-\alpha}$ with $\alpha\approx0.23$ in moiré systems), saturation of MCD signals at $T_K$, and anomalous Hall jumps at ferromagnetic onset [2310.06044].

## 5. Variants and Generalizations: Moiré Kondo Lattices and Impurity Models

Recent realizations in gate-tunable moiré Kondo lattices reveal a platform for studying Kondo destruction and emergent magnetism with high control [2310.06044]. In AB-stacked MoTe$_2$/WSe$_2$, as carrier density $x$ is decreased, $T_K\to0$ and a heavy Fermi liquid transitions to a ferromagnetic Anderson insulator at $x_c\sim0.04$. This is characterized by:
- A resistivity exponent $R_{xx}\sim T^{-0.23}$ at $x_c$.
- Diverging effective mass $m^*\sim\sqrt{A}$ and localization length $\xi$.
- Onset of ferromagnetic order (MCD, anomalous Hall effect) nearly concomitant with Kondo breakdown.
- Transition criterion $J_\text{RKKY} \gtrsim k_BT_K$, with $J_\text{RKKY}\sim x^{-2}$ and $T_K$ rapidly suppressed near $x_c$.

Impurity and few-spin models (two-impurity Kondo, Kondo triangle) [1503.05091, 2002.12338] reveal that Kondo breakdown can occur as a first-order (entanglement-jump) transition, exhibit topological order, or show deconfinement phenomena, further enriching the taxonomy of possible QCPs.

## 6. Emergent Phases and Topological Aspects

Kondo-breakdown transitions can enable the emergence of exotic quantum phases:
- **Fractionalized Fermi Liquids ($FL^*$)**: A phase with decoupled spinon Fermi surface, emergent gauge fields, and small conduction Fermi surface; separated from the heavy Fermi liquid by a Kondo-breakdown transition [1312.0764, 2311.13641].
- **Chiral heavy-fermion metals**: Intermediate phases with time-reversal and translation symmetry breaking, generically predicted at the Kondo-breakdown QCP when emergent fluxes couple to Kondo hybridization [2311.13641].
- **Phase separation and charge-spin coupled criticality**: In valence-fluctuating Anderson–Heisenberg lattices, strong valence fluctuations near Kondo breakdown can render the transition first order, inducing phase separation or inhomogeneous states due to Coulomb interaction [2208.12827].

## 7. Methodologies and Critical Exponents

Quantitative diagnostics of the Kondo-breakdown QPT rely on:
- **Numerical approaches**: Density-matrix renormalization group (DMRG) for 1D models [1102.2573, 1803.06570], large-$N$ Schwinger-boson mean-field, and parton mean-field theory [1901.10411, 2311.13641].
- **EDMFT combined with NRG**: For computation of both dynamical and static susceptibilities, identification of lines of locally critical points, and extraction of exponents $\alpha, \gamma, \nu, \beta$ (with $\alpha\sim0.73$, $\nu\sim1$, $\beta\sim1/2$ in Ising-anisotropic models) [1603.03829].
- **Critical behavior**: Typical exponents observed include fractional $\alpha\approx0.75$, $\nu\sim 1/2$, and scaling functions demonstrating superscaling invariance as a function of quantum fluctuation tuning parameter [1603.03829].

## 8. Distinction from Spin-Density-Wave QCPs

The Kondo-breakdown QPT differs fundamentally from the Landau (SDW) picture:
- SDW QCPs involve only order-parameter (magnetic) fluctuations, no Fermi surface jump, and exhibit Gaussian critical exponents with dynamic exponent $z=2$ for AFM, $z=3$ for FM [1012.5440, 1303.4141, 1312.0764].
- Kondo-breakdown QCPs involve both magnetic and Kondo-singlet criticality, FS volume jumps, non-Gaussian exponents, emergent scales ($E^*$ or $T^*_{\rm loc}$), and $\omega/T$ scaling in both spin and single-particle response.

## 9. Open Issues and Future Directions

Key current issues and avenues for research include:
- Precise characterization of universality classes in lower dimensions and under frustration, disorder, or strong valence fluctuations [2208.12827, 1901.10411].
- Impact of topology and emergent gauge structure on quantum criticality and resulting metallic/insulating phases (topological Kondo insulators, chiral metals) [2311.13641].
- Engineering and control of Kondo breakdown and quantum criticality in designer platforms (moiré heterostructures), including direct electrical, thermal, and spectroscopic control [2310.06044].
- Detailed exploration of phase separation and intrinsically inhomogeneous critical states near Kondo breakdown transitions.

Current and prospective experiments—especially those enabling direct FS reconstruction, anomalous transport, and controlled tuning of model parameters—continue to sharpen the distinction between Kondo-breakdown and conventional quantum criticality in correlated electron systems.

Source: https://www.emergentmind.com/topics/kondo-breakdown-quantum-phase-transition